By Jacques Vicens (Editor), Jack Harrowfield (Editor)
Calixarenes were generally exploited in all components of supramolecular chemistry over the last 3 a long time and plenty of fresh advancements have involved their functions within the creation of chemical entities with the size of nanometres, as in
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Association constants therefore were estimated from rate constants for the dissociation and association processes, as determined by FRET measurements11 (see below). Values of 106 M–1 to 108 M–1 for homodimers of tetraaryl ureas explain why monomeric compounds are not observed under the conditions of usual NMR experiments. To compare the relative “stability” of different dimers in a given solvent, increasing amounts of a hydrogen bond breaking solvent like DMSO-d6 can be added to determine how much is needed to destroy the dimer.